Issue 3, 2008
From the journal:

Chemical Communications

The mechanism of carbonate formation on Pd–Al2O3 catalysts†

Karin Föttinger,a   Robert Schlöglb  and  Günther Rupprechter*a  

* Corresponding authors

a Institute of Materials Chemistry, Veterinärplatz 1, Vienna, Austria
E-mail: grupp@imc.tuwien.ac.at
Fax: +43 1 25077 3890
Tel: +43 1 25077 3813

b Fritz Haber Institute, Max Planck Society, Faradayweg 4-6, Berlin, Germany
Fax: +49 30 8413 4404
Tel: +49 30 8413 4401

Abstract

Vibrational spectroscopic investigations of the adsorption of isotopically labelled and unlabelled CO and CO2 reveal that carbonate formation on Pd–alumina catalysts occurs via an “oxygen down” reaction of CO with hydroxyl groups on the support, whereas CO dissociation on Pd can be excluded.

Graphical abstract: The mechanism of carbonate formation on Pd–Al2O3 catalysts

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Article information

DOI
https://doi.org/10.1039/B713161E
Article type
Communication
Submitted
28 Aug 2007
Accepted
15 Oct 2007
First published
25 Oct 2007

Chem. Commun., 2008, 320-322

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The mechanism of carbonate formation on Pd–Al2O3 catalysts

K. Föttinger, R. Schlögl and G. Rupprechter, Chem. Commun., 2008, 320 DOI: 10.1039/B713161E

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