Issue 2, 2008
From the journal:

Chemical Communications

Direct synthesis of porous organosilicas containing chiral organic groups within their framework and a new analytical method for enantiomeric purity of organosilicas†

Shinji Inagaki,*ab   Shiyou Guan,‡a   Qihua Yang,§a   Mahendra P. Kapoora  and  Toyoshi Shimada*bc  

* Corresponding authors

a Toyota Central R&D Labs., Inc., Nagakute, Aichi 480-1192, Japan
E-mail: inagaki@mosk.tytlabs.co.jp
Fax: +81-561-63-6507
Tel: +81-561-71-7393

b Core Research and Evolution Science and Technology (CREST), Japan Science and Technology (JST), Japan

c Department of Chemical Engineering, Nara National College of Technology, 22 Yata-cho, Yamatokoriyama, Nara 639-1080, Japan
E-mail: shimada@chem.nara-k.ac.jp
Fax: +81-743-55-6154
Tel: + 81-743-55-6154

Abstract

Organosilica porous solids containing chiral organic moieties in the framework with an enantiomeric purity of 95% ee, estimated by eluting organic constituent units from chiral organosilicas, were synthesized from a newly designed chiral (R)-(+)-1,2-bis(trimethoxysilyl)phenylethane precursor via a surfactant-mediated self-assembly approach.

Graphical abstract: Direct synthesis of porous organosilicas containing chiral organic groups within their framework and a new analytical method for enantiomeric purity of organosilicas

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Article information

DOI
https://doi.org/10.1039/B714163G
Article type
Communication
Submitted
13 Sep 2007
Accepted
11 Oct 2007
First published
17 Oct 2007

Chem. Commun., 2008, 202-204

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Direct synthesis of porous organosilicas containing chiral organic groups within their framework and a new analytical method for enantiomeric purity of organosilicas

S. Inagaki, S. Guan, Q. Yang, M. P. Kapoor and T. Shimada, Chem. Commun., 2008, 202 DOI: 10.1039/B714163G

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