Issue 2, 2008
From the journal:

Chemical Communications

Chemo- and enantioselective sulfoxidation of bis(ethylenedithio)-tetrathiafulvalene (BEDT-TTF) into chiral BEDT-TTF-sulfoxide†

Marcos Chas,a   Margareth Lemarié,b   Mihaela Guleab  and  Narcis Avarvari*a  

* Corresponding authors

a Laboratoire Chimie, Ingénierie Moléculaire et Matériaux (CIMMA), UMR 6200 CNRS-Université d'Angers, UFR Sciences, Bât. K, 2 Bd. Lavoisier, France
E-mail: narcis.avarvari@univ-angers.fr
Fax: 33 2 41 73 50 84
Tel: 33 2 41 73 54 05

b Laboratoire de Chimie Moléculaire et Thio-Organique, ENSICAEN, Université de Caen Basse-Normandie, CNRS, 6 Boulevard du Maréchal Juin, France

Abstract

Selective sulfoxidation of BEDT-TTF (bis(ethylenedithio)-tetrathiafulvalene) with enantiopure (camphoryl-sulfonyl)oxaziridine derivatives provided the inner monosulfoxide, as demonstrated using single crystal X-ray analysis, with an enantiomeric excess of 44% (up to 74% after recrystallization).

Graphical abstract: Chemo- and enantioselective sulfoxidation of bis(ethylenedithio)-tetrathiafulvalene (BEDT-TTF) into chiral BEDT-TTF-sulfoxide

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Article information

DOI
https://doi.org/10.1039/B714245E
Article type
Communication
Submitted
14 Sep 2007
Accepted
11 Oct 2007
First published
23 Oct 2007

Chem. Commun., 2008, 220-222

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Chemo- and enantioselective sulfoxidation of bis(ethylenedithio)-tetrathiafulvalene (BEDT-TTF) into chiral BEDT-TTF-sulfoxide

M. Chas, M. Lemarié, M. Gulea and N. Avarvari, Chem. Commun., 2008, 220 DOI: 10.1039/B714245E

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