Issue 4, 2008
From the journal:

Chemical Communications

A stable zerovalent palladium chain enveloped by a π-electron sheath of conjugated polyene ligands†

Yasuki Tatsumi,a   Tetsuro Murahashi,*a   Mitsue Okada,a   Sensuke Ogoshia  and  Hideo Kurosawaa  

* Corresponding authors

a Department of Applied Chemistry, Osaka University, & PRESTO, Japan Science and Technology Agency (JST), Suita, Osaka, Japan
E-mail: tetsu@chem.eng.osaka-u.ac.jp
Fax: (+81)6 6879 7394
Tel: (+81)6 6879 7374

Abstract

A surprisingly stable homoleptic Pd04 chain complex of non-activated olefins was isolated and structurally characterized by X-ray crystallographic analysis, and the unique structure and bonding are compared to those of the corresponding dicationic [Pd4]2+ chain sandwich complex.

Graphical abstract: A stable zerovalent palladium chain enveloped by a π-electron sheath of conjugated polyene ligands

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Article information

DOI
https://doi.org/10.1039/B714530F
Article type
Communication
Submitted
20 Sep 2007
Accepted
31 Oct 2007
First published
13 Nov 2007

Chem. Commun., 2008, 477-479

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A stable zerovalent palladium chain enveloped by a π-electron sheath of conjugated polyene ligands

Y. Tatsumi, T. Murahashi, M. Okada, S. Ogoshi and H. Kurosawa, Chem. Commun., 2008, 477 DOI: 10.1039/B714530F

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