Issue 5, 2008
From the journal:

Chemical Communications

Facile assembly of hybrid materials containing polyoxometalate cluster anions and organic dyecations: crystal structures and initial spectral characterization†

Jingli Xie,*ab   Brendan F. Abrahamsa  and  Anthony G. Wedd*ab  

* Corresponding authors

a School of Chemistry, The University of Melbourne, Parkville, Victoria 3052, Australia
E-mail: xij@unimelb.edu.au, agw@unimelb.edu.au
Fax: +61 (3)9347 5180
Tel: +61 (3)8344 2377

b Bio21 Molecular Science and Biotechnology Institute, The University of Melbourne, Parkville, Victoria 3010, Australia

Abstract

Salts of the pararosaniline dye cation and four polyoxometalate cluster anions have been isolated under both ambient and hydrothermal conditions; structural and initial spectroscopic data are consistent with significant perturbation of ion electronic states induced by charge-assisted N–H⋯O hydrogen bonds.

Graphical abstract: Facile assembly of hybrid materials containing polyoxometalate cluster anions and organic dye cations: crystal structures and initial spectral characterization

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Article information

DOI
https://doi.org/10.1039/B715288D
Article type
Communication
Submitted
04 Oct 2007
Accepted
16 Nov 2007
First published
28 Nov 2007

Chem. Commun., 2008, 576-578

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Facile assembly of hybrid materials containing polyoxometalate cluster anions and organic dye cations: crystal structures and initial spectral characterization

J. Xie, B. F. Abrahams and A. G. Wedd, Chem. Commun., 2008, 576 DOI: 10.1039/B715288D

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