Issue 8, 2008
From the journal:

Chemical Communications

Remarkable acceleration of cyanosilylation by the mesoporous Al-MCM-41 catalyst†

Katsuyuki Iwanami,a   Jun-Chul Choi,a   Baowang Lu,a   Toshiyasu Sakakuraa  and  Hiroyuki Yasuda*a  

* Corresponding authors

a National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, Tsukuba, Ibaraki 305-8565, Japan
E-mail: h.yasuda@aist.go.jp
Fax: +81 29 861 4580
Tel: +81 29 861 4559

Abstract

The presence of the heterogeneous mesoporous Al-MCM-41 catalyst remarkably accelerated the cyanosilylation of various aldehydes and ketones with trialkylsilyl cyanide, giving the corresponding cyanohydrin silyl ethers in quantitative yields under mild reaction conditions.

Graphical abstract: Remarkable acceleration of cyanosilylation by the mesoporous Al-MCM-41 catalyst

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Article information

DOI
https://doi.org/10.1039/B718462J
Article type
Communication
Submitted
29 Nov 2007
Accepted
11 Jan 2008
First published
23 Jan 2008

Chem. Commun., 2008, 1002-1004

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Remarkable acceleration of cyanosilylation by the mesoporous Al-MCM-41 catalyst

K. Iwanami, J. Choi, B. Lu, T. Sakakura and H. Yasuda, Chem. Commun., 2008, 1002 DOI: 10.1039/B718462J

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