Large mixed metal nitride clusters encapsulated in a small cage: the confinement of the C68-based clusterfullerenes

Shangfeng Yang; Alexey A. Popov; Lothar Dunsch

doi:10.1039/B803200A

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Large mixed metal nitride clusters encapsulated in a small cage: the confinement of the C₆₈-based clusterfullerenes†

Shangfeng Yang,*^ab Alexey A. Popov^ac and Lothar Dunsch*^a

Author affiliations

* Corresponding authors

^a Group of Electrochemistry and Conducting Polymers, Leibniz-Institute for Solid State and Materials Research (IFW) Dresden, D-01171 Dresden, Germany
E-mail: l.dunsch@ifw-dresden.de
Fax: +49(351)4659 811
Tel: +49(351)4659 660

^b Hefei National Laboratory for Physical Sciences at Microscale & Department of Materials Science and Engineering, University of Science and Technology of China, Hefei, China
E-mail: sfyang@ustc.edu.cn
Fax: +86(551)3601 750
Tel: +86(551)3601 750

^c Department of Chemistry, Moscow State University, Leninskiye Gory, 119992 Moscow, Russia

Abstract

Three novel C₆₈-based mixed metal nitride clusterfullerenes, which comprise of a small non-IPR C₆₈ cage encapsulating large nitride clusters including DySc₂N, LuSc₂N, and Lu₂ScN, have been synthesized and isolated, resulting in overpassing the confinement of the C₆₈ cage.

Download options Please wait...

Supplementary files

Synthesis of M–Sc mixed metal NCFs and detailed isolations of 1–3, comparison of the colors of 1–3 and Sc3N@C68 solutions (in toluene) PDF (134K)

Article information

DOI: https://doi.org/10.1039/B803200A
Article type: Communication
Submitted: 25 Feb 2008
Accepted: 17 Mar 2008
First published: 18 Apr 2008

Download Citation

Chem. Commun., 2008, 2885-2887

Permissions

Request permissions

Large mixed metal nitride clusters encapsulated in a small cage: the confinement of the C₆₈-based clusterfullerenes

S. Yang, A. A. Popov and L. Dunsch, Chem. Commun., 2008, 2885 DOI: 10.1039/B803200A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications