Issue 33, 2008
From the journal:

Chemical Communications

Manipulating the cavity of a porous material changes the photoreactivity of included guests†

Mahender B. Dewal,a   Yuewen Xu,a   Jun Yang,a   Fiaz Mohammed,a   Mark D. Smitha  and  Linda S. Shimizu*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of South Carolina, Columbia, South Carolina, USA
E-mail: shimizul@mail.chem.sc.edu
Fax: +1 803-777-9521
Tel: +1 803-777-2066

Abstract

Changing an ether to a ketone within the framework of a bis-urea macrocycle has little effect on the supramolecular assembly of this building block into porous crystals but introduces a triplet sensitizer into the framework that dramatically alters the photochemical reactions of included guests.

Graphical abstract: Manipulating the cavity of a porous material changes the photoreactivity of included guests

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B805895D
Article type
Communication
Submitted
09 Apr 2008
Accepted
07 May 2008
First published
30 Jun 2008

Chem. Commun., 2008, 3909-3911

Permissions

Request permissions

Manipulating the cavity of a porous material changes the photoreactivity of included guests

M. B. Dewal, Y. Xu, J. Yang, F. Mohammed, M. D. Smith and L. S. Shimizu, Chem. Commun., 2008, 3909 DOI: 10.1039/B805895D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements