A simple route to novel D spherosilicones; the first crystallographic structures of D6 and D8 cages

Alan R. Bassindale; Zhihua Liu; Peter G. Taylor; Peter N. Horton; Michael B. Hursthouse

doi:10.1039/B808456D

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A simple route to novel D spherosilicones; the first crystallographic structures of D₆ and D₈ cages†

Alan R. Bassindale,*^a Zhihua Liu,^a Peter G. Taylor,*^a Peter N. Horton^b and Michael B. Hursthouse^b

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* Corresponding authors

^a Department of Chemistry and Analytical Sciences, Open University, Walton Hall, Milton Keynes, UK
E-mail: P.G.Taylor@open.ac.uk
Tel: +441908 652512

^b EPSRC National Crystallography Service, University of Southampton, Highfield, Southampton, UK

Abstract

The synthesis, characterisation and crystal structure of D₈ and D₆ cages from the corresponding bis(dialkoxy)methane is reported.

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Article information

DOI: https://doi.org/10.1039/B808456D
Article type: Communication
Submitted: 19 May 2008
Accepted: 16 Jul 2008
First published: 29 Sep 2008

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Chem. Commun., 2008, 5625-5627

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A simple route to novel D spherosilicones; the first crystallographic structures of D₆ and D₈ cages

A. R. Bassindale, Z. Liu, P. G. Taylor, P. N. Horton and M. B. Hursthouse, Chem. Commun., 2008, 5625 DOI: 10.1039/B808456D

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Chemical Communications