Issue 41, 2008
From the journal:

Chemical Communications

Heavier group 2 element-catalysed hydroamination of isocyanates†

Anthony G. M. Barrett,*b   Tanya C. Boorman,a   Mark R. Crimmin,b   Michael S. Hill,*a   Gabriele Kociok-Köhna  and  Panayiotis A. Procopiouc  

* Corresponding authors

a Department of Chemistry, University of Bath, Claverton Down, Bath, UK

b Department of Chemistry, Imperial College London, Exhibition Road, South Kensington, London, UK

c GlaxoSmithKline Medicines Research Centre, Gunnels Wood Road, Stevenage, Hertfordshire, UK

Abstract

The heteroleptic calcium amides [{ArNC(Me)CHC(Me)NAr}Ca(NR2)(THF)] (Ar = 2,6-di-iso-propylphenyl, R = SiMe3, Ph) and the homoleptic heavier alkaline earth amides, [M{N(SiMe3)2}2] (M = Ca, Sr and Ba) are reported as pre-catalysts for the hydroamination of isocyanates.

Graphical abstract: Heavier group 2 element-catalysed hydroamination of isocyanates

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Article information

DOI
https://doi.org/10.1039/B809649J
Article type
Communication
Submitted
09 Jun 2008
Accepted
28 Jul 2008
First published
12 Sep 2008

Chem. Commun., 2008, 5206-5208

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Heavier group 2 element-catalysed hydroamination of isocyanates

A. G. M. Barrett, T. C. Boorman, M. R. Crimmin, M. S. Hill, G. Kociok-Köhn and P. A. Procopiou, Chem. Commun., 2008, 5206 DOI: 10.1039/B809649J

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