Issue 47, 2008
From the journal:

Chemical Communications

Novel three-dimensional 3d–4f microporous magnets exhibiting selective gas adsorption behavior†

Cui-Jin Li,a   Zhuo-jia Lin,a   Meng-Xia Peng,ab   Ji-Dong Leng,a   Ming-Mei Yangac  and  Ming-Liang Tong*a  

* Corresponding authors

a MOE Key Laboratory of Bioinorganic and Synthetic Chemistry/State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, P. R. China
E-mail: tongml@mail.sysu.edu.cn

b Department of Chemistry, Jiaying University, P. R. China

c Department of Chemistry, Guangxi Teachers Education University, P. R. China

Abstract

Three microporous Ln-Co-pyta heterometallic compounds [Ln4Co3(pyta)6(H2O)9]·5H2O (Ln = Sm (1), Eu (2), Gd (3); H3pyta = 2,4,6-pyridinetricarboxylic acid) have interesting selective adsorption abilities towards H2/N2 and CO2/N2 because of size-selective effects; magnetic analysis reveals that 3 has a ferromagnetic behavior.

Graphical abstract: Novel three-dimensional 3d–4f microporous magnets exhibiting selective gas adsorption behavior

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Article information

DOI
https://doi.org/10.1039/B815024A
Article type
Communication
Submitted
28 Aug 2008
Accepted
24 Sep 2008
First published
29 Oct 2008

Chem. Commun., 2008, 6348-6350

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Novel three-dimensional 3d–4f microporous magnets exhibiting selective gas adsorption behavior

C. Li, Z. Lin, M. Peng, J. Leng, M. Yang and M. Tong, Chem. Commun., 2008, 6348 DOI: 10.1039/B815024A

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