Issue 45, 2008

Modular chiral dendritic monodentate phosphoramidite ligands for Rh(ii)-catalyzed asymmetric hydrogenation: unprecedented enhancement of enantioselectivity

Abstract

Modular chiral dendrimers with monodentate phosphoramidite ligands located at the core were synthesized and applied in the Rh-catalyzed asymmetric hydrogenations, afforded unprecedented enhancement of enantioselectivity.

Graphical abstract: Modular chiral dendritic monodentate phosphoramidite ligands for Rh(ii)-catalyzed asymmetric hydrogenation: unprecedented enhancement of enantioselectivity

Supplementary files

Article information

Article type
Communication
Submitted
03 Sep 2008
Accepted
30 Sep 2008
First published
15 Oct 2008

Chem. Commun., 2008, 6048-6050

Modular chiral dendritic monodentate phosphoramidite ligands for Rh(II)-catalyzed asymmetric hydrogenation: unprecedented enhancement of enantioselectivity

F. Zhang, Y. Li, Z. Li, Y. He, S. Zhu, Q. Fan and Q. Zhou, Chem. Commun., 2008, 6048 DOI: 10.1039/B815380A

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