Issue 7, 2008
From the journal:

CrystEngComm

[Co(phen3)]2[Cu11I15]: a mixed-metal iodocuprate containing the novel [Cu10I15]5− and [Cu12I15]3−clusters†

Meredith A. Tershansy,a   Andrea M. Goforth,a   Joseph M. Ellsworth,a   Mark D. Smitha  and  Hans-Conrad zur Loye*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of South Carolina, Columbia, USA
E-mail: zurloye@mail.chem.sc.edu
Fax: +1-803-777-8508
Tel: +1-803-777-6916

Abstract

A new mixed-metal compound, [Co(phen3)]2[Cu11I15] (phen = 1,10-phenanthroline), containing the two novel copper(I) iodide anionic clusters [Cu10I15]5− and [Cu12I15]3−, has been synthesized solvothermally and structurally characterized by single crystal X-ray diffraction. The synthesis and structures of the two clusters are presented and the extensive edge-to-face and offset face-to-face interactions between the [Co(phen3)]2+ cations are described.

Graphical abstract: [Co(phen3)]2[Cu11I15]: a mixed-metal iodocuprate containing the novel [Cu10I15]5− and [Cu12I15]3−clusters

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B716031C
Article type
Paper
Submitted
17 Oct 2007
Accepted
05 Feb 2008
First published
03 Mar 2008

CrystEngComm, 2008,10, 833-838

Permissions

Request permissions

[Co(phen3)]2[Cu11I15]: a mixed-metal iodocuprate containing the novel [Cu10I15]5− and [Cu12I15]3−clusters

M. A. Tershansy, A. M. Goforth, J. M. Ellsworth, M. D. Smith and H. zur Loye, CrystEngComm, 2008, 10, 833 DOI: 10.1039/B716031C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements