Issue 5, 2008
From the journal:

CrystEngComm

Structural transformations from a 1-D chain to two 3-D supramolecular isomers via crystal disassembly and reassembly†‡§

Yue-Ling Bai,a   Jun Tao,*a   Rong-Bin Huanga  and  Lan-Sun Zhenga  

* Corresponding authors

a Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, People's Republic of China
E-mail: taojun@xmu.edu.cn

Abstract

The reaction of L(−)-malic acid (L-H2mal), manganese salts and triethylamine in methanol–water solution gave a 1-D chiral complex, [MnII(L-mal)(H2O)(CH3OH)]2 (1), which could be rationally controlled to transform into 3-D supramolecular isomers [MnII(L-mal)(H2O)2]·H2O (2a and 2b, respectively).

Graphical abstract: Structural transformations from a 1-D chain to two 3-D supramolecular isomers via crystal disassembly and reassembly

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Article information

DOI
https://doi.org/10.1039/B717297D
Article type
Communication
Submitted
08 Nov 2007
Accepted
03 Jan 2008
First published
23 Jan 2008

CrystEngComm, 2008,10, 472-474

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Structural transformations from a 1-D chain to two 3-D supramolecular isomers via crystal disassembly and reassembly

Y. Bai, J. Tao, R. Huang and L. Zheng, CrystEngComm, 2008, 10, 472 DOI: 10.1039/B717297D

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