A mixed-linker porphyrin framework with CdI2-type topology

Eun-Young Choi; Paul M. Barron; Richard W. Novotney; Chunhua Hu; Young-UK Kwon; Wonyoung Choe

doi:10.1039/B720035H

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A mixed-linker porphyrin framework with CdI₂-type topology†

Eun-Young Choi,^a Paul M. Barron,^a Richard W. Novotney,^a Chunhua Hu,^b Young-UK Kwon^c and Wonyoung Choe*^a

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* Corresponding authors

^a Department of Chemistry, University of Nebraska, Lincoln, NE, USA
E-mail: choe2@unlnotes.unl.edu
Fax: +(402)472-9402
Tel: +(402)472-0751

^b Nebraska Center for Materials and Nanoscience, University of Nebraska, Lincoln, NE, USA

^c Department of Chemistry, BK-21 School of Chemical Materials Science, Sungkyunkwan University, Suwon, Korea

Abstract

A novel metal–organic framework, [(Co(cis-ZnDCPP)(bpy)]·4DMF·H₂O (cis-ZnDCPP = zinc 5,10-di(4-carboxyphenyl)-15,20-diphenylporphyrin; bpy = 4,4′-bipyridine; DMF = dimethyl formamide), has been synthesized from the solvothermal reaction and exhibits unique CdI₂ layers constructed from paddle-wheel buiding units, Co₂(COO)₄, cis-ZnDCPP, and 4,4′-bipyridine linker.

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Article information

DOI: https://doi.org/10.1039/B720035H
Article type: Communication
Submitted: 02 Jan 2008
Accepted: 18 Mar 2008
First published: 09 Apr 2008

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CrystEngComm, 2008,10, 824-826

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A mixed-linker porphyrin framework with CdI₂-type topology

E. Choi, P. M. Barron, R. W. Novotney, C. Hu, Y. Kwon and W. Choe, CrystEngComm, 2008, 10, 824 DOI: 10.1039/B720035H

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