Issue 7, 2008
From the journal:

CrystEngComm

Rare example of a polynuclear heterometallic yttrium(III)–copper(I) iodide cluster with a [Y6(μ6-O)(μ3-OH)8]8+ core structure showing single crystal-to-single crystal transformation†‡

Shashank Mishra,*a   Erwann Jeanneau,b   Stéphane Daniele*a  and  Liliane G. Hubert-Pfalzgraf§a  

* Corresponding authors

a Université Lyon 1, IRCELYON-UMR 5401, 2 Avenue A. Einstein, Villeurbanne, France
E-mail: mishrashashank74@rediffmail.com
Fax: +33 472445399
Tel: +33 472445329

b Université Lyon 1, Centre de Diffractométrie, Villeurbanne, France

Abstract

A colorless polynuclear heterometallic yttrium(III)–copper(I) iodide cluster [Y6(μ6-O)(μ3-OH)8(DMSO)16(H2O)2]8+ [Cu2I4]2−6[I]− (1), isolated in a moderate yield from the hydrolytic reaction of [Y(DMSO)6(DMF)2][CuI3][I] in acetonitrile, undergoes unique crystal-to-crystal transformation to give reddish-yellow cluster [Y6(μ6-O)(μ3-OH)8(DMSO)14(H2O)4]8+ 2[CuI3]2−3[I]− [I3]− (2).

Graphical abstract: Rare example of a polynuclear heterometallic yttrium(III)–copper(I) iodide cluster with a [Y6(μ6-O)(μ3-OH)8]8+ core structure showing single crystal-to-single crystal transformation

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Article information

DOI
https://doi.org/10.1039/B802434K
Article type
Communication
Submitted
12 Feb 2008
Accepted
28 Feb 2008
First published
25 Mar 2008

CrystEngComm, 2008,10, 814-816

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Rare example of a polynuclear heterometallic yttrium(III)–copper(I) iodide cluster with a [Y6(μ6-O)(μ3-OH)8]8+ core structure showing single crystal-to-single crystal transformation

S. Mishra, E. Jeanneau, S. Daniele and L. G. Hubert-Pfalzgraf, CrystEngComm, 2008, 10, 814 DOI: 10.1039/B802434K

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