Issue 33, 2008
From the journal:

Dalton Transactions

6-Coordinate tungsten(vi) tris-n-isopropylanilide complexes: products of terminal oxo and nitrido transformations effected by main group electrophiles†‡

Christopher R. Clough,a   Peter Müllera  and  Christopher C. Cummins*a  

* Corresponding authors

a Room 6-435, Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, MA, United States of America

Abstract

The nitridotungsten(VI) complex NW(N[i-Pr]Ar)3 (1-N, Ar = 3,5-Me2C6H3) reacts with (CF3C(O))2O followed by ClSiMe3 to give the isolable trifluoroacetylimido-chloride complex 1-(NC(O)CF3)Cl, with oxalyl chloride to give cyanate-dichloride 1-(OCN)(Cl)2, and with PCl5 to give trichlorophosphinimide-dichloride 1-(NPCl3)(Cl)2. The oxo-chloride complex 1-(O)Cl, obtained from 1-N upon treatment with pivaloyl chloride, reacts with PCl5 to give trichloride 1-(Cl)3. Synthetic and structural details are reported for the new tungsten trisanilide derivatives.

Graphical abstract: 6-Coordinate tungsten(vi) tris-n-isopropylanilide complexes: products of terminal oxo and nitrido transformations effected by main group electrophiles

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B801037D
Article type
Paper
Submitted
21 Jan 2008
Accepted
03 Mar 2008
First published
01 Jul 2008

Dalton Trans., 2008, 4458-4463

Permissions

Request permissions

6-Coordinate tungsten(VI) tris-n-isopropylanilide complexes: products of terminal oxo and nitrido transformations effected by main group electrophiles

C. R. Clough, P. Müller and C. C. Cummins, Dalton Trans., 2008, 4458 DOI: 10.1039/B801037D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements