Issue 2, 2009
From the journal:

Chemical Communications

Oxygenation of alkylzinc complexes with pyrrolylketiminate ligand: access to alkylperoxide versusoxo-encapsulated complexes†‡

Janusz Lewiński,*ab   Karolina Suwała,a   Tomasz Kaczorowski,a   Michał Gałęzowski,c   Daniel T. Gryko,c   Iwona Justyniakb  and  Janusz Lipkowskib  

* Corresponding authors

a Department of Chemistry, Warsaw University of Technology, Noakowskiego, 3, 00-664 Warsaw, Poland
E-mail: lewin@ch.pw.edu.pl

b Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland

c Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland

Abstract

By variation of the zinc bonded alkyl group significantly different post-oxygenation products, the novel zinc alkylperoxide and the tetranuclear zinc oxo-encapsulated cluster, were derived from the controlled oxygenation of the corresponding alkylzinc complexes with a pyrrolylketiminate ligand.

Graphical abstract: Oxygenation of alkylzinc complexes with pyrrolylketiminate ligand: access to alkylperoxide versusoxo-encapsulated complexes

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Article information

DOI
https://doi.org/10.1039/B813315H
Article type
Communication
Submitted
31 Jul 2008
Accepted
03 Oct 2008
First published
17 Nov 2008

Chem. Commun., 2009, 215-217

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Oxygenation of alkylzinc complexes with pyrrolylketiminate ligand: access to alkylperoxide versusoxo-encapsulated complexes

J. Lewiński, K. Suwała, T. Kaczorowski, M. Gałęzowski, D. T. Gryko, I. Justyniak and J. Lipkowski, Chem. Commun., 2009, 215 DOI: 10.1039/B813315H

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