Issue 4, 2008
From the journal:

Chemical Communications

Switched role of fullerene in the Diels–Alder reaction: facile addition of dienophiles to the conjugated fullerenediene moiety†

Jiayao Yao,a   Zuo Xiao,a   Jianxin Zhang,a   Xiaobing Yang,a   Liangbing Gan*ab  and  Wen-Xiong Zhang*a  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of the Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing, China
E-mail: gan@pku.edu.cn, wx_zhang@pku.edu.cn
Fax: (+) 86-10-62751708

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai, China

Abstract

The isolated cyclopentadiene moiety in a fullerene multi-adduct derivative reacts readily with dienophiles to form [4 + 2] cycloaddition products.

Graphical abstract: Switched role of fullerene in the Diels–Alder reaction: facile addition of dienophiles to the conjugated fullerenediene moiety

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Article information

DOI
https://doi.org/10.1039/B817300A
Article type
Communication
Submitted
02 Oct 2008
Accepted
27 Oct 2008
First published
11 Nov 2008

Chem. Commun., 2008

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Switched role of fullerene in the Diels–Alder reaction: facile addition of dienophiles to the conjugated fullerenediene moiety

J. Yao, Z. Xiao, J. Zhang, X. Yang, L. Gan and W. Zhang, Chem. Commun., 2008 DOI: 10.1039/B817300A

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