Issue 5, 2009
From the journal:

Chemical Communications

Relaying stereochemistry through aromatic ureas: 1,9 and 1,15 remote stereocontrol†

Jonathan Clayden,*a   Mark Pickwortha  and  Lyn H. Jonesb  

* Corresponding authors

a School of Chemistry, University of Manchester, Oxford Road, Manchester, UK
E-mail: Clayden@man.ac.uk

b Pfizer Central Research, Sandwich, Kent, UK

Abstract

The well-defined conformation of an N,N′-diarylurea allows a chiral sulfinyl substituent to influence diastereoselectivity in the formation of new stereogenic centres up to 14 bond lengths away.

Graphical abstract: Relaying stereochemistry through aromatic ureas: 1,9 and 1,15 remote stereocontrol

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Article information

DOI
https://doi.org/10.1039/B817527F
Article type
Communication
Submitted
06 Oct 2008
Accepted
10 Nov 2008
First published
26 Nov 2008

Chem. Commun., 2009, 547-549

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Relaying stereochemistry through aromatic ureas: 1,9 and 1,15 remote stereocontrol

J. Clayden, M. Pickworth and L. H. Jones, Chem. Commun., 2009, 547 DOI: 10.1039/B817527F

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