Issue 14, 2009
From the journal:

Chemical Communications

Synthesis and reactivity of a bis(dimesitylboryl)azaborine and its fluoride sensing ability†

Tomohiro Agou,a   Masaki Sekine,a   Junji Kobayashia  and  Takayuki Kawashima*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, Japan
E-mail: takayuki@chem.s.u-tokyo.ac.jp
Fax: +81-3-5800-6899
Tel: +81-3-5800-6899

Abstract

An azaborine bearing two dimesitylboryl groups on its periphery showed very strong light absorption and moderate photo-luminescence emission; the reaction of the title compound with fluoride ion resulted in multi-step fluoride ion complexation on the boron atoms of the dimesitylboryl groups, producing mono- and bisfluoroborates.

Graphical abstract: Synthesis and reactivity of a bis(dimesitylboryl)azaborine and its fluoride sensing ability

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Article information

DOI
https://doi.org/10.1039/B818505K
Article type
Communication
Submitted
20 Oct 2008
Accepted
15 Jan 2009
First published
20 Feb 2009

Chem. Commun., 2009, 1894-1896

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Synthesis and reactivity of a bis(dimesitylboryl)azaborine and its fluoride sensing ability

T. Agou, M. Sekine, J. Kobayashi and T. Kawashima, Chem. Commun., 2009, 1894 DOI: 10.1039/B818505K

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