Issue 15, 2009
From the journal:

Chemical Communications

A metal–organic framework based on an unprecedented nonanuclear cluster as a secondary building unit: structure and gas sorption behavior†

Mira Park,a   Dohyun Moon,a   Ji Woong Yoon,b   Jong-San Changb  and  Myoung Soo Lah*a  

* Corresponding authors

a Department of Chemistry and Applied Chemistry, Hanyang University, Ansan, Kyunggi-do, Korea
E-mail: mslah@hanyang.ac.kr
Fax: +82 31 436 8100
Tel: +82 31 400 5496

b Korea Research Institute of Chemical Technology, Daejeon, Korea

Abstract

A 3D chiral microporous metal–organic framework containing a nonanuclear cluster as a secondary building unit was prepared using a bent and rigid dicarboxylic ligand, 2,7-naphthalene dicarboxylic acid, and the zinc ion, where a nonanuclear cluster with potential exposed metal sites is in the form of a corner-sharing cyclic trimer of a tetrahedral Zn4O motif.

Graphical abstract: A metal–organic framework based on an unprecedented nonanuclear cluster as a secondary building unit: structure and gas sorption behavior

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Article information

DOI
https://doi.org/10.1039/B818648K
Article type
Communication
Submitted
21 Oct 2008
Accepted
04 Feb 2009
First published
26 Feb 2009

Chem. Commun., 2009, 2026-2028

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A metal–organic framework based on an unprecedented nonanuclear cluster as a secondary building unit: structure and gas sorption behavior

M. Park, D. Moon, J. W. Yoon, J. Chang and M. S. Lah, Chem. Commun., 2009, 2026 DOI: 10.1039/B818648K

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