Issue 16, 2009
From the journal:

Chemical Communications

An organogel system can control the stereochemical course of anthracene photodimerization†‡

Arnab Dawn,§a   Norifumi Fujita,*a   Shuichi Haraguchi,a   Kazuki Sadaa  and  Seiji Shinkai§*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka 819-0395, Japan

Abstract

A novel photoresponsive organogel with a binary gelator containing 2-anthracenecarboxylic acid shows a high degree of stereochemical control, resulting in head-to-head photocyclodimers exclusively together with significant enantiomeric excess induced by the chiral counterpart of the gelator.

Graphical abstract: An organogel system can control the stereochemical course of anthracene photodimerization

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Article information

DOI
https://doi.org/10.1039/B820565E
Article type
Communication
Submitted
18 Nov 2008
Accepted
29 Jan 2009
First published
09 Feb 2009

Chem. Commun., 2009, 2100-2102

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An organogel system can control the stereochemical course of anthracene photodimerization

A. Dawn, N. Fujita, S. Haraguchi, K. Sada and S. Shinkai, Chem. Commun., 2009, 2100 DOI: 10.1039/B820565E

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