Issue 13, 2009
From the journal:

Chemical Communications

Synthesis and structure of air-stable Lewis acidic binuclear complex of zirconocene pentafluorophenylsulfonate and its catalytic application in the allylation of carbonyl compounds with tetraallyltin†

Renhua Qiu,a   Xinhua Xu,*a   Yinhui Li,a   Guoping Zhang,a   Lingling Shao,a   Delie An*a  and  Shuangfeng Yin*a  

* Corresponding authors

a College of Chemistry and Chemical Engineering, Hunan University, Changsha, China
E-mail: xhx1581@yahoo.com.cn, deliean@sina.com, sfyin73@yahoo.com.cn
Fax: +86-731-511-8161
Tel: +86-731-511-8161

Abstract

Air-stable Lewis acidic μ2-hydroxy bridged binuclear complex of zirconocene pentafluorophenylsulfonate was successfully synthesized and found to show high catalytic efficiency in chemoselective allylation of carbonyl compounds with tetraallyltin in aqueous methanol media.

Graphical abstract: Synthesis and structure of air-stable Lewis acidic binuclear complex of zirconocene pentafluorophenylsulfonate and its catalytic application in the allylation of carbonyl compounds with tetraallyltin

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Article information

DOI
https://doi.org/10.1039/B821366F
Article type
Communication
Submitted
28 Nov 2008
Accepted
19 Jan 2009
First published
12 Feb 2009

Chem. Commun., 2009, 1679-1681

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Synthesis and structure of air-stable Lewis acidic binuclear complex of zirconocene pentafluorophenylsulfonate and its catalytic application in the allylation of carbonyl compounds with tetraallyltin

R. Qiu, X. Xu, Y. Li, G. Zhang, L. Shao, D. An and S. Yin, Chem. Commun., 2009, 1679 DOI: 10.1039/B821366F

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