Issue 29, 2009

A four-shell, 136-metal 3d-4f heterometallic cluster approximating a rectangular parallelepiped

Abstract

A nanosized heterometallic cluster containing 60 La(III) and 76 Ni(II) ions, which are arranged into a four-shell, nest-like framework structure, was obtained by the hydrolytic reaction of the mixed La(NO3)3–Ni(NO3)2 system using iminodiacetate as an ancillary ligand to control the hydrolysis.

Graphical abstract: A four-shell, 136-metal 3d-4f heterometallic cluster approximating a rectangular parallelepiped

Supplementary files

Article information

Article type
Communication
Submitted
16 Dec 2008
Accepted
20 Mar 2009
First published
06 Apr 2009

Chem. Commun., 2009, 4354-4356

A four-shell, 136-metal 3d-4f heterometallic cluster approximating a rectangular parallelepiped

X. Kong, L. Long, R. Huang, L. Zheng, T. D. Harris and Z. Zheng, Chem. Commun., 2009, 4354 DOI: 10.1039/B822609A

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