A three-dimensional adamantane-like nanoscopic cage built from four iodide-bridged triangular Mo3S7cluster units

Larry R. Falvello; Rosa Llusar; Sonia Triguero; Cristian Vicent

doi:10.1039/B823223G

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A three-dimensional adamantane-like nanoscopic cage built from four iodide-bridged triangular Mo₃S₇cluster units†

Larry R. Falvello,^a Rosa Llusar,*^b Sonia Triguero^b and Cristian Vicent*^c

Author affiliations

* Corresponding authors

^a Departamento de Química Inorgánica and I.C.M.A, Universidad de Zaragoza-C.S.I.C, Spain
Fax: +34-976 76118

^b Departament de Química Física i Analítica, Universitat Jaume I, Av. Sos Baynat s/n, Castello, Spain
E-mail: Rosa.Llusar@qfa.uji.es

^c Serveis Centrals d’Instrumentació Científica, Universitat Jaume I, Av. Sos Baynat s/n, Castelló, Spain
E-mail: barrera@sg.uji.es

Abstract

Chemical oxidation of a Mo₃S₇cluster featuring catecholate ligands, namely [Mo₃S₇(Cl₄cat)₃]²⁻ (Cl₄cat = tetrachlorocatecholate), allows the isolation of a unique nanoscopic molecular cage made of four iodide-bridged Mo₃S₇clusters as the kinetically favoured product.

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Article information

DOI: https://doi.org/10.1039/B823223G
Article type: Communication
Submitted: 24 Dec 2008
Accepted: 30 Mar 2009
First published: 05 May 2009

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Chem. Commun., 2009, 3440-3442

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A three-dimensional adamantane-like nanoscopic cage built from four iodide-bridged triangular Mo₃S₇cluster units

L. R. Falvello, R. Llusar, S. Triguero and C. Vicent, Chem. Commun., 2009, 3440 DOI: 10.1039/B823223G

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