Issue 13, 2009
From the journal:

Chemical Communications

Helicity induction on water-soluble oligoresorcinols in alkaline water and their application to chirality sensing†‡

Hidetoshi Goto,§a   Yoshio Furusho*ab  and  Eiji Yashima*ab  

* Corresponding authors

a Yashima Super-structured Helix Project, Exploratory Research for Advanced Technology (ERATO), Japan Science and Technology Agency (JST), Japan

b Department of Molecular Design and Engineering, Graduate School of Engineering, Nagoya University, Chikusa-ku, Nagoya, Japan
E-mail: furusho@apchem.nagoya-u.ac.jp, yashima@apchem.nagoya-u.ac.jp
Fax: +81-52-789-3185

Abstract

Oligoresorcinol oligomers were found to adopt a single-stranded helical conformation in alkaline water through intramolecular hydrogen bonds, of which a helix-sense bias was induced by the addition of water-soluble chiral compounds, such as ammonium salts, amines and alcohols.

Graphical abstract: Helicity induction on water-soluble oligoresorcinols in alkaline water and their application to chirality sensing

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Article information

DOI
https://doi.org/10.1039/B900113A
Article type
Communication
Submitted
05 Jan 2009
Accepted
15 Jan 2009
First published
09 Feb 2009

Chem. Commun., 2009, 1650-1652

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Helicity induction on water-soluble oligoresorcinols in alkaline water and their application to chirality sensing

H. Goto, Y. Furusho and E. Yashima, Chem. Commun., 2009, 1650 DOI: 10.1039/B900113A

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