Issue 17, 2009

Oxidized forms of a tripyrrane: α-tripyrrinone, β-tripyrrinone and a C2 symmetric hexapyrrole

Abstract

α- and β-tripyrrinone isomers (36), and a C2 symmetric hexapyrrole (7) were isolated from the oxidation of meso-perfluorophenyl tripyrrane1 (and meso-2,6-dichlorophenyl tripyrrane2) with DDQ under aerobic conditions, and the structure of 3 was determined by X-ray crystallographic analysis.

Graphical abstract: Oxidized forms of a tripyrrane: α-tripyrrinone, β-tripyrrinone and a C2 symmetric hexapyrrole

Supplementary files

Article information

Article type
Communication
Submitted
19 Jan 2009
Accepted
24 Feb 2009
First published
25 Mar 2009

Chem. Commun., 2009, 2323-2325

Oxidized forms of a tripyrrane: α-tripyrrinone, β-tripyrrinone and a C2 symmetric hexapyrrole

J. Shin, S. S. Hepperle, B. O. Patrick and D. Dolphin, Chem. Commun., 2009, 2323 DOI: 10.1039/B901171B

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