Anion-induced contraction of helical receptors†
Abstract
Uptake of a tetrafluoroborate anion into the centre of a dicopper bis-salicylaldoxime complex causes a major contraction of the cavity and an increase in helicity.
* Corresponding authors
a
Institute of Fundamental Sciences, Massey University, Private Bag 11 222, Palmerston North, New Zealand
E-mail:
p.g.plieger@massey.ac.nz
Fax: +64 6 350 5682
Tel: +64 6 356 9099 Ext 7825
b
School of Chemistry, University of Edinburgh, Edinburgh, UK
E-mail:
Peter.Tasker@ed.ac.uk
Fax: +44 131 650 6543
Tel: +44 131 650 4706
Uptake of a tetrafluoroborate anion into the centre of a dicopper bis-salicylaldoxime complex causes a major contraction of the cavity and an increase in helicity.
M. Wenzel, G. B. Jameson, L. A. Ferguson, Q. W. Knapp, R. S. Forgan, F. J. White, S. Parsons, P. A. Tasker and P. G. Plieger, Chem. Commun., 2009, 3606 DOI: 10.1039/B902772F
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