Issue 27, 2009
From the journal:

Chemical Communications

Boryl ligands and their roles in metal-catalysed borylation reactions

Li Dang,a   Zhenyang Lin*a  and  Todd B. Marder*b  

* Corresponding authors

a Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong
E-mail: chzlin@ust.hk
Fax: +852-2358-1594
Tel: +852-2358-7379

b Department of Chemistry, Durham University, South Road, Durham, UK
E-mail: todd.marder@durham.ac.uk
Fax: +44-191-384-4737
Tel: +44-191-334-2037

Abstract

In this feature article, we discuss selected recent aspects of metal boryl (M–BR2) chemistry pertaining, in particular, to the role of late and post-transition metal boryl complexes in various catalytic processes. The exceptionally strong σ-donor properties of boryl ligands and their related nucleophilic behaviour are highlighted.

Graphical abstract: Boryl ligands and their roles in metal-catalysed borylation reactions

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Article information

DOI
https://doi.org/10.1039/B903098K
Article type
Feature Article
Submitted
13 Feb 2009
Accepted
06 Apr 2009
First published
18 May 2009

Chem. Commun., 2009, 3987-3995

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Boryl ligands and their roles in metal-catalysed borylation reactions

L. Dang, Z. Lin and T. B. Marder, Chem. Commun., 2009, 3987 DOI: 10.1039/B903098K

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