The trinity of polyoxometalates: connecting {M12} Keggin and {M18} Dawson clusters to triangles

Scott G. Mitchell; Sumit Khanra; Haralampos N. Miras; Thomas Boyd; De-Liang Long; Leroy Cronin

doi:10.1039/B903206A

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The trinity of polyoxometalates: connecting {M₁₂} Keggin and {M₁₈} Dawson clusters to triangles†

Scott G. Mitchell,‡^a Sumit Khanra,‡^a Haralampos N. Miras,^a Thomas Boyd,^a De-Liang Long^a and Leroy Cronin*^a

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* Corresponding authors

^a WestCHEM, Department of Chemistry, University of Glasgow, Joseph Black Building, University Avenue, Glasgow, UK
E-mail: L.Cronin@chem.gla.ac.uk
Web: www.croninlab.com
Fax: +44 (0)141 330 4888
Tel: +44 (0)141 330 6650

Abstract

Two topologically equivalent triangular POM aggregates based upon the Keggin (1) and Dawson (2) cluster species, with distinctive double {W–O–M} intra-molecular linkages involving Mn^III and Co^III ions are presented; both these compounds demonstrate electrocatalytic activity.

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Article information

DOI: https://doi.org/10.1039/B903206A
Article type: Communication
Submitted: 16 Feb 2009
Accepted: 23 Mar 2009
First published: 16 Apr 2009

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Chem. Commun., 2009, 2712-2714

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The trinity of polyoxometalates: connecting {M₁₂} Keggin and {M₁₈} Dawson clusters to triangles

S. G. Mitchell, S. Khanra, H. N. Miras, T. Boyd, D. Long and L. Cronin, Chem. Commun., 2009, 2712 DOI: 10.1039/B903206A

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