Issue 19, 2009
From the journal:

Chemical Communications

Highly oxidized diiron complexes: generation, spectroscopy, and stabilities†

Julia Bernhardette Hildegard Strautmann,a   Carl-Georg Freiherr von Richthofen,a   Serena DeBeer George,b   Eberhard Bothe,c   Eckhard Billc  and  Thorsten Glaser*a  

* Corresponding authors

a Fakultät für Chemie, Universität Bielefeld, Universitätsstrasse 25, Bielefeld, Germany
E-mail: thorsten.glaser@uni-bielefeld.de
Fax: +49 (0)521 106 6003
Tel: +49 (0)521 106 6105

b Stanford Synchrotron Radiation Lightsource, SLAC, Stanford University, Stanford, USA

c Max-Planck-Institut für Bioanorganische Chemie, Stiftstrasse 34-36, Mülheim, Germany

Abstract

Oxidation of the diferric complex [LFeIIIOFeIIIL] to the monoradical complex [LFeIIIOFeIIIL˙]+ and the diradical complex [L˙FeIIIOFeIIIL˙]2+ is followed by a decay into monomeric complexes including a highly reactive putative [LFeIV[double bond, length as m-dash]O] complex.

Graphical abstract: Highly oxidized diiron complexes: generation, spectroscopy, and stabilities

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B903500A
Article type
Communication
Submitted
18 Feb 2009
Accepted
23 Mar 2009
First published
07 Apr 2009

Chem. Commun., 2009, 2637-2639

Permissions

Request permissions

Highly oxidized diiron complexes: generation, spectroscopy, and stabilities

J. B. H. Strautmann, C. Freiherr von Richthofen, S. DeBeer George, E. Bothe, E. Bill and T. Glaser, Chem. Commun., 2009, 2637 DOI: 10.1039/B903500A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements