Issue 42, 2009
From the journal:

Chemical Communications

Coordination chemistry approach to the long-standing challenge of stereocontrolled chemical glycosylation†

Papapida Pornsuriyasak,a   Cornelia Vetter,b   Sophon Kaeothip,a   Michael Kovermann,cd   Jochen Balbach,cd   Dirk Steinborn*b  and  Alexei V. Demchenko*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Missouri—St. Louis, One University Boulevard, St. Louis, Missouri 63121, USA
E-mail: demchenkoa@umsl.edu

b Institut für Chemie-Anorganische Chemie, Martin-Luther-Universität Halle-Wittenberg, D-06120 Halle, Kurt-Mothes Straße 2, Germany
E-mail: dirk.steinborn@chemie.uni-halle.de

c Institut für Physik, Fachgruppe Biophysik, Martin-Luther-Universität Halle-Wittenberg, D-06099 Halle (Saale), Germany

d Mitteldeutsches Zentrum für Struktur und Dynamik der Proteine (MZP), Martin-Luther-Universität Halle-Wittenberg, D-06099 Halle (Saale), Germany

Abstract

This study clearly demonstrates that a multi-dentate metal coordination to the leaving group, along with O-5 and/or a protecting group at O-6, has a strong effect on the stereoselectivity of chemical glycosylation.

Graphical abstract: Coordination chemistry approach to the long-standing challenge of stereocontrolled chemical glycosylation

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Article information

DOI
https://doi.org/10.1039/B903942B
Article type
Communication
Submitted
25 Feb 2009
Accepted
08 Sep 2009
First published
24 Sep 2009

Chem. Commun., 2009, 6379-6381

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Coordination chemistry approach to the long-standing challenge of stereocontrolled chemical glycosylation

P. Pornsuriyasak, C. Vetter, S. Kaeothip, M. Kovermann, J. Balbach, D. Steinborn and A. V. Demchenko, Chem. Commun., 2009, 6379 DOI: 10.1039/B903942B

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