Issue 28, 2009
From the journal:

Chemical Communications

A heterocyclic organogallium peroxide with two dialkylgallium groups bridged by a peroxide dianion†

Werner Uhl,*a   Mohammad Reza Halvagara  and  Marcus Layha  

* Corresponding authors

a Institut für Anorganische und Analytische Chemie der Universität Münster, Corrensstraße 30, 48149 Münster, Germany
E-mail: uhlw@uni-muenster.de
Fax: +49 251 36660

Abstract

Treatment of Li[H2GaR2] 1 [R = CH(SiMe3)2] with the hydrogen peroxide adduct (H2O2)2·DABCO (DABCO = diazabicyclooctane) afforded a heterocyclic digallium peroxide, [R2Ga(μ,η1,η1-O2)(μ-OH)GaR2]Li(DABCO) (2), in which two dialkylgallium groups are bridged by an oxidizing peroxo and a hydroxo ligand.

Graphical abstract: A heterocyclic organogallium peroxide with two dialkylgallium groups bridged by a peroxide dianion

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B906392G
Article type
Communication
Submitted
31 Mar 2009
Accepted
18 May 2009
First published
09 Jun 2009

Chem. Commun., 2009, 4269-4271

Permissions

Request permissions

A heterocyclic organogallium peroxide with two dialkylgallium groups bridged by a peroxide dianion

W. Uhl, M. R. Halvagar and M. Layh, Chem. Commun., 2009, 4269 DOI: 10.1039/B906392G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements