Germanium-73 NMR of amorphous and crystalline GeO2

Vladimir K. Michaelis; Pedro M. Aguiar; Victor V. Terskikh; Scott Kroeker

doi:10.1039/B906642J

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Germanium-73 NMR of amorphous and crystalline GeO₂†

Vladimir K. Michaelis,^a Pedro M. Aguiar,^b Victor V. Terskikh^c and Scott Kroeker*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, University of Manitoba, Winnipeg, Manitoba, Canada
E-mail: Scott_Kroeker@umanitoba.ca
Fax: +1 204 474 7608
Tel: +1 204 474 9335

^b Commissariat à l’Énergie Atomique, IRAMIS, Laboratoire de Structure et Dynamique par Résonance Magnétique, Gif-sur-Yvette, France
E-mail: pedro.aguiar@cea.fr

^c Steacie Institute for Molecular Sciences, National Research Council, Ottawa, ON, Canada
E-mail: Victor.Terskikh@nrc-cnrc.gc.ca
Fax: +1 613 990 1555
Tel: +1 613 998 5552

Abstract

Ultrahigh-field ⁷³Ge NMR spectra and DFT calculations of GeO₂ phases reveal distinct parameters for four- and six-coordinate Ge, illustrating the viability of solid-state ⁷³Ge NMR for structural studies.

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Supplementary files

Experimental procedure and non-spinning spectra ofquartz-phase GeO₂ at 11.7 T and spectral simulation at 21.1 T PDF (543K)

Article information

DOI: https://doi.org/10.1039/B906642J
Article type: Communication
Submitted: 03 Apr 2009
Accepted: 07 May 2009
First published: 27 May 2009

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Chem. Commun., 2009, 4660-4662

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Germanium-73 NMR of amorphous and crystalline GeO₂

V. K. Michaelis, P. M. Aguiar, V. V. Terskikh and S. Kroeker, Chem. Commun., 2009, 4660 DOI: 10.1039/B906642J

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