Issue 32, 2009
From the journal:

Chemical Communications

Through-space π-delocalized Pillar[5]arene†

Tomoki Ogoshi,*a   Kenji Umeda,a   Tada-aki Yamagishia  and  Yoshiaki Nakamoto*a  

* Corresponding authors

a Department of Chemistry and Chemical Engineering, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan
E-mail: ogoshi@t.kanazawa-u.ac.jp
Fax: +81 76-234-4775
Tel: +81 76-234-4800

Abstract

Pillar[5]arene from modified phenylethynyl groups was prepared; since the repeating π-conjugated units were largely π-delocalized via the through-space within the cavity, it showed temperature- and solvent-responsive blue-green emission.

Graphical abstract: Through-space π-delocalized Pillar[5]arene

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Article information

DOI
https://doi.org/10.1039/B907894K
Article type
Communication
Submitted
21 Apr 2009
Accepted
24 Jun 2009
First published
14 Jul 2009

Chem. Commun., 2009, 4874-4876

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Through-space π-delocalized Pillar[5]arene

T. Ogoshi, K. Umeda, T. Yamagishi and Y. Nakamoto, Chem. Commun., 2009, 4874 DOI: 10.1039/B907894K

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