Issue 36, 2009

Recent development of reactions with α-diazocarbonyl compounds as nucleophiles

Abstract

The nucleophilicaddition reaction of diazo-compound derived anions or enolates with electrophilic C[double bond, length as m-dash]O and C[double bond, length as m-dash]N bonds have been summarized. The subsequent reactions of the addition products demonstrate diverse reactivities of the diazocarbonyl compounds bearing other functional groups and their potential in organic synthesis. Asymmetric catalysis is also possible with diazocarbonyl compounds as nucleophiles.

Graphical abstract: Recent development of reactions with α-diazocarbonyl compounds as nucleophiles

Article information

Article type
Feature Article
Submitted
28 Apr 2009
Accepted
11 Jun 2009
First published
22 Jul 2009

Chem. Commun., 2009, 5350-5361

Recent development of reactions with α-diazocarbonyl compounds as nucleophiles

Y. Zhang and J. Wang, Chem. Commun., 2009, 5350 DOI: 10.1039/B908378B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements