Issue 29, 2009
From the journal:

Chemical Communications

Zirconocene-mediated ligand-switched selective cleavage of active and inert carbon–carbon bonds in allylcyclopropanes†

Chao Wang,a   Liang Deng,a   Jun Yan,a   Hailin Wang,a   Qian Luo,a   Wen-Xiong Zhanga  and  Zhenfeng Xi*ab  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, 202, Chengfu Rd, Beijing 100871, China
E-mail: zfxi@pku.edu.cn
Fax: +86 6275 9728
Tel: +86 6275 9643

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

Abstract

Selective cleavage of both active and inert C–C bonds in substituted allylcyclopropanes was realized via a novel ligand-controlled approach using zirconocene(II)-1-butene or zirconocene(II)-benzyne complexes.

Graphical abstract: Zirconocene-mediated ligand-switched selective cleavage of active and inert carbon–carbon bonds in allylcyclopropanes

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Article information

DOI
https://doi.org/10.1039/B908803B
Article type
Communication
Submitted
05 May 2009
Accepted
01 Jun 2009
First published
11 Jun 2009

Chem. Commun., 2009, 4414-4416

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Zirconocene-mediated ligand-switched selective cleavage of active and inert carbon–carbon bonds in allylcyclopropanes

C. Wang, L. Deng, J. Yan, H. Wang, Q. Luo, W. Zhang and Z. Xi, Chem. Commun., 2009, 4414 DOI: 10.1039/B908803B

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