Polyoxometalate-based {MnIII2}–Schiff base composite materials exhibiting single-molecule magnet behaviour

Qiong Wu; Yang-Guang Li; Yong-Hui Wang; Rodolphe Clérac; Ying Lu; En-Bo Wang

doi:10.1039/B909246C

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Polyoxometalate-based {Mn^III₂}–Schiff base composite materials exhibiting single-molecule magnet behaviour†

Qiong Wu,^a Yang-Guang Li,*^a Yong-Hui Wang,^a Rodolphe Clérac,*^bc Ying Lu^a and En-Bo Wang*^a

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* Corresponding authors

^a Key Laboratory of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Renmin Street No.5268, Changchun, Jilin, P. R. China
E-mail: liyg658@nenu.edu.cn, wangeb889@nenu.edu.cn

^b CNRS, UPR 8641, Centre de Recherche Paul Pascal (CRPP), Equipe “Matériaux Moléculaires Magnétiques”, 115 avenue du Dr Albert Schweitzer, Pessac, France
E-mail: clerac@crpp-bordeaux.cnrs.fr

^c Université de Bordeaux, UPR 8641, Pessac, France

Abstract

The introduction of [Mn(salen)(H₂O)]₂(ClO₄)₂·H₂O ({Mn^III₂}) into the polyoxometalate (POM) systems Na₃[XMo₆(OH)₆O₁₈] (X = Al and Cr) led to the isolation of new {Mn^III₂}–POM composite materials with single-molecule magnetic behaviour.

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Article information

DOI: https://doi.org/10.1039/B909246C
Article type: Communication
Submitted: 11 May 2009
Accepted: 13 Aug 2009
First published: 03 Sep 2009

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Chem. Commun., 2009, 5743-5745

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Polyoxometalate-based {Mn^III₂}–Schiff base composite materials exhibiting single-molecule magnet behaviour

Q. Wu, Y. Li, Y. Wang, R. Clérac, Y. Lu and E. Wang, Chem. Commun., 2009, 5743 DOI: 10.1039/B909246C

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