Issue 38, 2009

Polyoxometalate-based {MnIII2}–Schiff base composite materials exhibiting single-molecule magnet behaviour

Abstract

The introduction of [Mn(salen)(H2O)]2(ClO4)2·H2O ({MnIII2}) into the polyoxometalate (POM) systems Na3[XMo6(OH)6O18] (X = Al and Cr) led to the isolation of new {MnIII2}–POM composite materials with single-molecule magnetic behaviour.

Graphical abstract: Polyoxometalate-based {MnIII2}–Schiff base composite materials exhibiting single-molecule magnet behaviour

Supplementary files

Article information

Article type
Communication
Submitted
11 May 2009
Accepted
13 Aug 2009
First published
03 Sep 2009

Chem. Commun., 2009, 5743-5745

Polyoxometalate-based {MnIII2}–Schiff base composite materials exhibiting single-molecule magnet behaviour

Q. Wu, Y. Li, Y. Wang, R. Clérac, Y. Lu and E. Wang, Chem. Commun., 2009, 5743 DOI: 10.1039/B909246C

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