Phosphinidene        group-transfer with a phospha-Wittig reagent: a new entry to transition metal phosphorus multiple bonds

Uriah J. Kilgore; Hongjun Fan; Maren Pink; Eugenijus Urnezius; John D. Protasiewicz; Daniel J. Mindiola

doi:10.1039/B910410K

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Phosphinidene group-transfer with a phospha-Wittig reagent: a new entry to transition metal phosphorus multiple bonds†

Uriah J. Kilgore,^a Hongjun Fan,^a Maren Pink,^a Eugenijus Urnezius,^b John D. Protasiewicz*^b and Daniel J. Mindiola*^a

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* Corresponding authors

^a Department of Chemistry and the Molecular Structure Center, Indiana University Bloomington, USA
E-mail: mindiola@indiana.edu
Fax: +1 812 855 8300
Tel: +1 812 855 2399

^b Department of Chemistry, Case Western Reserve University, Cleveland, USA
E-mail: protasiewicz@case.edu
Fax: +1 216 368 3006
Tel: +1 216 368 5060

Abstract

The phosphanylidene-σ⁴-phosphorane reagents Me₃P [double bond, length as m-dash] PAr (Ar = 2,4,6-^tBu₃C₆H₂ and 2,6-Mes₂C₆H₃) are good delivery vehicles of the terminal phosphinidene moiety, PAr, to early-transition metals composed of zirconium and vanadium.

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Article information

DOI: https://doi.org/10.1039/B910410K
Article type: Communication
Submitted: 27 May 2009
Accepted: 15 Jun 2009
First published: 06 Jul 2009

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Chem. Commun., 2009, 4521-4523

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Phosphinidene group-transfer with a phospha-Wittig reagent: a new entry to transition metal phosphorus multiple bonds

U. J. Kilgore, H. Fan, M. Pink, E. Urnezius, J. D. Protasiewicz and D. J. Mindiola, Chem. Commun., 2009, 4521 DOI: 10.1039/B910410K

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