Issue 36, 2009
From the journal:

Chemical Communications

Ferrocenes with two carbohydrate appendages at the upper and lower rings are useful for investigating carbohydrate–carbohydrate interactions†

Atsushi Otsuka,ab   Kunihiro Sakuraiab  and  Teruaki Hasegawa*ab  

* Corresponding authors

a Department of Life Sciences, Faculty of Life Sciences, Toyo University, 1-1-1 Izumino, Itakura-machi, Ora-gun 374-0193, Japan
E-mail: t-hasegawa@toyonet.toyo.ac.jp
Fax: +81 276 82 9215
Tel: +81 276 82 9215

b Bio-Nano Electronics Research Centre, Toyo University, 2100 Kujirai, Kawagoe 350-8585, Japan

Abstract

The conformation of ferrocene with two βLac appendages is changed on addition of Ca2+ and Na+, which can be ascribed to intramolecular βLac–βLac interactions mediated by these cations and the resultant stabilization of twisted rotamers along the Cp–Fe–Cp axis.

Graphical abstract: Ferrocenes with two carbohydrate appendages at the upper and lower rings are useful for investigating carbohydrate–carbohydrate interactions

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B910534D
Article type
Communication
Submitted
29 May 2009
Accepted
07 Jul 2009
First published
30 Jul 2009

Chem. Commun., 2009, 5442-5444

Permissions

Request permissions

Ferrocenes with two carbohydrate appendages at the upper and lower rings are useful for investigating carbohydrate–carbohydrate interactions

A. Otsuka, K. Sakurai and T. Hasegawa, Chem. Commun., 2009, 5442 DOI: 10.1039/B910534D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements