Issue 42, 2009
From the journal:

Chemical Communications

[(silox)3M]2(μ:η1,η1-P2) (M = Nb, Ta) and [(silox)3Nb]2{μ:η2,η2-(cP3–cP3)} from (silox)3M (M = NbPMe3, Ta) and P4 (silox = tBu3SiO)†

Elliott B. Hulley,a   Peter T. Wolczanski*a  and  Emil B. Lobkovskya  

* Corresponding authors

a Department of Chemistry & Chemical Biology, Baker Laboratory, Cornell University, Ithaca, USA
E-mail: ptw2@cornell.edu
Fax: +1 607 255 4137
Tel: +1 607 255 7220

Abstract

Complexes containing the μ:η1,η1-P2 binding mode of diphosphorus have been prepared, along with a P6-containing byproduct.

Graphical abstract: [(silox)3M]2(μ:η1,η1-P2) (M = Nb, Ta) and [(silox)3Nb]2{μ:η2,η2-(cP3–cP3)} from (silox)3M (M = NbPMe3, Ta) and P4 (silox = tBu3SiO)

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Article information

DOI
https://doi.org/10.1039/B911275H
Article type
Communication
Submitted
09 Jun 2009
Accepted
27 Aug 2009
First published
14 Sep 2009

Chem. Commun., 2009, 6412-6414

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[(silox)3M]2(μ:η1,η1-P2) (M = Nb, Ta) and [(silox)3Nb]2{μ:η2,η2-(cP3–cP3)} from (silox)3M (M = NbPMe3, Ta) and P4 (silox = tBu3SiO)

E. B. Hulley, P. T. Wolczanski and E. B. Lobkovsky, Chem. Commun., 2009, 6412 DOI: 10.1039/B911275H

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