Issue 36, 2009

Ketoximes to N-substituted thioamides viaPSCl3 mediated Beckmann rearrangement

Abstract

N-Substituted thioamides were accessed from ketoximes by utilising PSCl3 as a uniquely capable reagent to induce Beckmann rearrangement as well as to capture the intermediate nitrilium ion.

Graphical abstract: Ketoximes to N-substituted thioamides viaPSCl3 mediated Beckmann rearrangement

Supplementary files

Article information

Article type
Communication
Submitted
17 Jun 2009
Accepted
03 Jul 2009
First published
28 Jul 2009

Chem. Commun., 2009, 5409-5411

Ketoximes to N-substituted thioamides viaPSCl3 mediated Beckmann rearrangement

U. Pathak, L. K. Pandey, S. Mathur and M. V. S. Suryanarayana, Chem. Commun., 2009, 5409 DOI: 10.1039/B911844F

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