Issue 38, 2009
From the journal:

Chemical Communications

Dual reactivity of a photochemically-generated cyclic enyne–allene†

Alexander V. Kuzmina  and  Vladimir V. Popik*a  

* Corresponding authors

a Department of Chemistry, University of Georgia, Athens, Georgia 30602, USA
E-mail: vpopik@uga.edu
Fax: +1 (706) 542-9454
Tel: +1 (706) 542-1953

Abstract

A reactive ten-membered ring enyne–allene (τ25 °C = 5–6 min) is efficiently generated (Φ300 nm = 0.57) by UV irradiation of a thermally stable precursor in which a triple bond is masked as a cyclopropenone moiety.

Graphical abstract: Dual reactivity of a photochemically-generated cyclic enyne–allene

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Article information

DOI
https://doi.org/10.1039/B911871C
Article type
Communication
Submitted
17 Jun 2009
Accepted
27 Jul 2009
First published
14 Aug 2009

Chem. Commun., 2009, 5707-5709

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Dual reactivity of a photochemically-generated cyclic enyne–allene

A. V. Kuzmin and V. V. Popik, Chem. Commun., 2009, 5707 DOI: 10.1039/B911871C

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