Issue 37, 2009
From the journal:

Chemical Communications

Eliminating the need for independent counterions in the construction of metal–organic rotaxane frameworks (MORFs)†

Lisa K. Knight,a   V. Nicholas Vukotic,a   Elizabeth Viljoen,a   Christopher B. Caputoa  and  Stephen J. Loeb*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Windsor, Windsor, Ontario, Canada
E-mail: loeb@uwindsor.ca
Fax: +1 519 973 7098
Tel: +1 519 253 3000 (3529)

Abstract

The combination of a disulfonated-dibenzo-24crown-8 ether wheel and a dicationic 1,2-bis(pyridinium)ethane axle yields a neutral [2]pseudorotaxane which in combination with neutral metallic units such as a Cu(II)benzoate paddlewheel or Cu(I)Br unit yields one-dimensional coordination polymers (linear and bent) which are the first examples of charge neutral, metal–organic rotaxane frameworks.

Graphical abstract: Eliminating the need for independent counterions in the construction of metal–organic rotaxane frameworks (MORFs)

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Article information

DOI
https://doi.org/10.1039/B911889F
Article type
Communication
Submitted
17 Jun 2009
Accepted
07 Aug 2009
First published
27 Aug 2009

Chem. Commun., 2009, 5585-5587

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Eliminating the need for independent counterions in the construction of metal–organic rotaxane frameworks (MORFs)

L. K. Knight, V. N. Vukotic, E. Viljoen, C. B. Caputo and S. J. Loeb, Chem. Commun., 2009, 5585 DOI: 10.1039/B911889F

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