Issue 38, 2009
From the journal:

Chemical Communications

A highly efficient methodology of asymmetric epoxidation based on a novel chiral sulfur ylide†‡

Francisco Sarabia,*a   Samy Chammaa,a   Miguel García-Castroa  and  Francisca Martín-Gálveza  

* Corresponding authors

a Department of Organic Chemistry, Faculty of Sciences, University of Malaga, Campus de Teatinos s/n, 29071-Malaga, Spain
E-mail: frsarabia@uma.es
Fax: +34 952 131941
Tel: +34 952 134258

Abstract

A new type of chiral sulfur ylides has been synthesized and their reactivities against carbonyl compounds tested, showing a high degree of stereoselectivity in the formation of transepoxyamides under very mild reaction conditions.

Graphical abstract: A highly efficient methodology of asymmetric epoxidation based on a novel chiral sulfur ylide

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Article information

DOI
https://doi.org/10.1039/B912070J
Article type
Communication
Submitted
19 Jun 2009
Accepted
22 Jul 2009
First published
07 Aug 2009

Chem. Commun., 2009, 5763-5765

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A highly efficient methodology of asymmetric epoxidation based on a novel chiral sulfur ylide

F. Sarabia, S. Chammaa, M. García-Castro and F. Martín-Gálvez, Chem. Commun., 2009, 5763 DOI: 10.1039/B912070J

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