Issue 47, 2009
From the journal:

Chemical Communications

Synthesis of fluorinated allenes viapalladium-catalyzed monofluoromethylation using FBSM†

Masamichi Ogasawara,*a   Hidetoshi Murakami,a   Tatsuya Furukawa,b   Tamotsu Takahashi*a  and  Norio Shibata*b  

* Corresponding authors

a Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita-ku, Sapporo 001-0021, Japan
E-mail: ogasawar@cat.hokudai.ac.jp, tamotsu@cat.hokudai.ac.jp
Fax: +81-11-706-9150

b Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya 466-8555, Japan
E-mail: nozshiba@nitech.ac.jp
Fax: +81-52-735-5442

Abstract

Palladium-catalyzed monofluoromethylation of substituted 2-bromo-1,3-dienes using fluorobis(phenylsulfonyl)methane (FBSM) as a pronucleophile gave previously unknown monofluoromethylated allenes in high yields, which are the isosteres of biologically attractive allenic alcohols.

Graphical abstract: Synthesis of fluorinated allenes viapalladium-catalyzed monofluoromethylation using FBSM

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Article information

DOI
https://doi.org/10.1039/B912531K
Article type
Communication
Submitted
25 Jun 2009
Accepted
16 Oct 2009
First published
02 Nov 2009

Chem. Commun., 2009, 7366-7368

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Synthesis of fluorinated allenes viapalladium-catalyzed monofluoromethylation using FBSM

M. Ogasawara, H. Murakami, T. Furukawa, T. Takahashi and N. Shibata, Chem. Commun., 2009, 7366 DOI: 10.1039/B912531K

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