Issue 41, 2009
From the journal:

Chemical Communications

Solvent-free direct reductive amination by catalytic use of an organotin reagent incorporated on an ionic liquid†

Phuoc Dien Pham,a   Philippe Bertusa  and  Stéphanie Legoupy*a  

* Corresponding authors

a Laboratoire de Synthèse Organique, UCO2M, UMR CNRS 6011, Université du Maine, Avenue Olivier Messiaen, 72085 Le Mans Cedex 9, France
E-mail: stephanie.legoupy@univ-lemans.fr
Fax: +33 2 43 83 39 02
Tel: +33 2 43 83 30 96

Abstract

An organotin reagent supported on an ionic liquid was used as a highly effective catalyst (down to 0.1 mol%) for the direct reductive amination of aldehydes and ketones using PhSiH3; this solvent-free method facilitates purification of the products, thus minimizing the contamination by tin.

Graphical abstract: Solvent-free direct reductive amination by catalytic use of an organotin reagent incorporated on an ionic liquid

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Article information

DOI
https://doi.org/10.1039/B912697J
Article type
Communication
Submitted
26 Jun 2009
Accepted
08 Sep 2009
First published
22 Sep 2009

Chem. Commun., 2009, 6207-6209

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Solvent-free direct reductive amination by catalytic use of an organotin reagent incorporated on an ionic liquid

P. D. Pham, P. Bertus and S. Legoupy, Chem. Commun., 2009, 6207 DOI: 10.1039/B912697J

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