Issue 37, 2009

Discrimination of cryptochirality in chiral isotactic polystyrene by asymmetric autocatalysis

Abstract

Chiral isotactic polystyrenes induce the enantioselective addition of diisopropylzinc to pyrimidine-5-carbaldehyde, affording the enantiomerically enriched pyrimidyl alkanol with the corresponding absolute configuration to that of cryptochiral polystyrenes in conjunction with asymmetric autocatalysis.

Graphical abstract: Discrimination of cryptochirality in chiral isotactic polystyrene by asymmetric autocatalysis

Supplementary files

Article information

Article type
Communication
Submitted
29 Jun 2009
Accepted
30 Jul 2009
First published
21 Aug 2009
This article is Open Access

Chem. Commun., 2009, 5621-5623

Discrimination of cryptochirality in chiral isotactic polystyrene by asymmetric autocatalysis

T. Kawasaki, C. Hohberger, Y. Araki, K. Hatase, K. Beckerle, J. Okuda and K. Soai, Chem. Commun., 2009, 5621 DOI: 10.1039/B912813A

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