Issue 40, 2009
From the journal:

Chemical Communications

Cage connectivities of C88 (33) and C92 (82) fullerenes captured as trifluoromethyl derivatives, C88(CF3)18 and C92(CF3)16†

Sergey I. Troyanov*a  and  Nadezhda B. Tamma  

* Corresponding authors

a Chemistry Department, Moscow State University, Moscow, Russia
E-mail: stroyano@thermo.chem.msu.ru
Fax: +7 495 9391240
Tel: +7 495 9395396

Abstract

The trifluoromethylation of a higher fullerene mixture followed by HPLC separation allowed the isolation and X-ray structural characterization of C1-C88(CF3)18 and D2-C92(CF3)16 compounds that turned out to be the derivatives of C2-C88 (isomer 33) and D2-C92 (isomer 82), respectively.

Graphical abstract: Cage connectivities of C88 (33) and C92 (82) fullerenes captured as trifluoromethyl derivatives, C88(CF3)18 and C92(CF3)16

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Article information

DOI
https://doi.org/10.1039/B912839E
Article type
Communication
Submitted
30 Jun 2009
Accepted
07 Aug 2009
First published
24 Aug 2009

Chem. Commun., 2009, 6035-6037

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Cage connectivities of C88 (33) and C92 (82) fullerenes captured as trifluoromethyl derivatives, C88(CF3)18 and C92(CF3)16

S. I. Troyanov and N. B. Tamm, Chem. Commun., 2009, 6035 DOI: 10.1039/B912839E

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